Jardine-Goerss chapter V treats simplicial groups and groupoids. For example, the category of sSets with an action of a simplicial group admits a model structure, and cofibrant objects correspond to principal -fibrations.
There is an equivalence of homotopy cats (probably a Quillen equivalence) between simplicial groups and reduced simplicial sets. Similarly for simplicial groupoids and simplicial sets. See Jardine-Goerss V.6. They also describe Milnor’s FK construction, a simplicial group being a fibrant model for .
nLab page on Simplicial group