Grothendieck developed in EGA a number of notions of smoothness for a scheme and, more generally, for a morphism of schemes. For algebraic varieties over a field, one already had a classical notion of a nonsingular variety.
A scheme of finite type over a field is smooth if after extension of scalars from to the algebraic closure it becomes a regular scheme, i.e. the stalks of its structure sheaf are regular local rings in the sense of commutative algebra.
A relative version of a smooth scheme is the notion of smooth morphism of schemes.
Specifically, a finitely presented commutative associative algebra over a field is smooth if either of the following equivalent conditions holds
the -module of Kähler differential forms is a projective object in ;
with regarded as an -bimodule in the evident way, it has a projective resolution.
For commutative -algebras a discussion is for instance around theorem 9.1.2 in
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