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\newtheorem{prop}{Proposition} \newtheorem{cor}{Corollary} \newtheorem*{utheorem}{Theorem} \newtheorem*{ulemma}{Lemma} \newtheorem*{uprop}{Proposition} \newtheorem*{ucor}{Corollary} \theoremstyle{definition} \newtheorem{defn}{Definition} \newtheorem{example}{Example} \newtheorem*{udefn}{Definition} \newtheorem*{uexample}{Example} \theoremstyle{remark} \newtheorem{remark}{Remark} \newtheorem{note}{Note} \newtheorem*{uremark}{Remark} \newtheorem*{unote}{Note} %------------------------------------------------------------------- \begin{document} %------------------------------------------------------------------- \section*{Schrödinger equation} \hypertarget{context}{}\subsubsection*{{Context}}\label{context} \hypertarget{physics}{}\paragraph*{{Physics}}\label{physics} [[!include physicscontents]] \hypertarget{equality_and_equivalence}{}\paragraph*{{Equality and Equivalence}}\label{equality_and_equivalence} [[!include equality and equivalence - contents]] \hypertarget{contents}{}\section*{{Contents}}\label{contents} \noindent\hyperlink{idea}{Idea}\dotfill \pageref*{idea} \linebreak \noindent\hyperlink{abstract}{Abstract}\dotfill \pageref*{abstract} \linebreak \noindent\hyperlink{definition}{Definition}\dotfill \pageref*{definition} \linebreak \noindent\hyperlink{properties}{Properties}\dotfill \pageref*{properties} \linebreak \noindent\hyperlink{decomposition_into_phase_and_amplitude}{Decomposition into phase and amplitude}\dotfill \pageref*{decomposition_into_phase_and_amplitude} \linebreak \noindent\hyperlink{examples}{Examples}\dotfill \pageref*{examples} \linebreak \noindent\hyperlink{related_concepts}{Related concepts}\dotfill \pageref*{related_concepts} \linebreak \noindent\hyperlink{references}{References}\dotfill \pageref*{references} \linebreak \hypertarget{idea}{}\subsection*{{Idea}}\label{idea} The Schr\"o{}dinger equation (named after [[Erwin Schrödinger]]) is the [[evolution equation]] of [[quantum mechanics]] in the [[Schrödinger picture]]. Its simplest version results from replacing the classical expressions in the nonrelativistic, mechanical equation for the energy of a point particle, by [[operators]] on a [[Hilbert space]]: We start with a point particle with mass $m$, impulse $p$ moving in the space $\mathbb{R}^3$ with a given potential function $V$, the energy of it is the sum of kinetic and potential energy: \begin{displaymath} E = \frac{p^2}{2 m} + V \end{displaymath} Quantizing this equation means replacing the coordinate $x \in \mathbb{R}^3$ with the [[Hilbert space]] $L^2(\mathbb{R}^3)$ and \begin{displaymath} E \to i \hbar \frac{\partial}{\partial t} \end{displaymath} \begin{displaymath} p \to -i \hbar \nabla \end{displaymath} with the [[Planck constant]] $h$ and \begin{displaymath} \hbar = \frac{h}{2 \pi} \end{displaymath} the reduced Planck constant. This results in the Schr\"o{}dinger equation for a single particle in a potential: \begin{displaymath} i \hbar \frac{\partial}{\partial t} \psi(t, x) = - \frac{\hbar^2}{2 m} \nabla^2 \psi(t, x) + V(t, x) \psi(t, x) \end{displaymath} The last term is the multiplication of the functions $V$ and $\psi$. The right hand side is called the [[Hamilton operator]] $H$, the Schr\"o{}dinger equation is therefore mostly stated in this form: \begin{displaymath} i \hbar \psi_t = H \psi \end{displaymath} \hypertarget{abstract}{}\subsection*{{Abstract}}\label{abstract} \ldots{} \hypertarget{definition}{}\subsection*{{Definition}}\label{definition} \ldots{} \hypertarget{properties}{}\subsection*{{Properties}}\label{properties} \hypertarget{decomposition_into_phase_and_amplitude}{}\subsubsection*{{Decomposition into phase and amplitude}}\label{decomposition_into_phase_and_amplitude} Consider for simplicity, the [[mechanical system]] of a [[particle]] of [[mass]] $m$ propagating on the [[real line]] $\mathbb{R}$ and subject to a [[potential]] $V \in C^\infty(\mathbb{R})$, so that the Schr\"o{}dinger equation is the [[differential equation]] on [[complex number|complex]]-valued [[functions]] $\Psi \colon \mathbb{R}\times \mathbb{R} \to \mathbb{C}$ given by \begin{displaymath} i \hbar \frac{\partial}{\partial t} \Psi = \frac{\hbar^2}{2m} \frac{\partial^2}{\partial^2 x} \Psi + V \Psi \,, \end{displaymath} where $\hbar$ denotes [[Planck's constant]]. By the nature of [[complex numbers]] and by the discussion at \emph{[[phase and phase space in physics]]}, it is natural to parameterize $\Psi$ -- away from its [[zero locus]] -- by a [[complex phase]] function \begin{displaymath} S \;\colon\; \mathbb{R}\times \mathbb{R} \longrightarrow \mathbb{R} \end{displaymath} and an [[absolute value]] function $\sqrt{\rho}$ \begin{displaymath} \sqrt{\rho} \;\colon\; \mathbb{R}\times \mathbb{R} \longrightarrow \mathbb{R} \end{displaymath} which is positive, $\sqrt{\rho} \gt 0$, as \begin{displaymath} \Psi \coloneqq \exp\left(\frac{i}{\hbar} S / \hbar\right) \sqrt{\rho} \,. \end{displaymath} Entering this Ansatz into the above Schr\"o{}dinger equation, that [[complex number|complex]] equation becomes equivalent to the following two [[real number|real]] equations: \begin{displaymath} \frac{\partial}{\partial t} S = - \frac{1}{2m} \left(\frac{\partial}{\partial x}S\right)^2 - V + \frac{\hbar^2}{2m} \frac{1}{\sqrt{\rho}}\frac{\partial^2}{\partial^2 x} \sqrt{\rho} \end{displaymath} and \begin{displaymath} \frac{\partial}{\partial t} \rho = - \frac{\partial}{\partial x} \left( \frac{1}{m} \left(\frac{\partial}{\partial x}S\right) \rho \right) \,. \end{displaymath} Now in this form one may notice a similarity of the form of these two equations with other equations from [[classical mechanics]] and [[statistical mechanics]]: \begin{enumerate}% \item The first equation is similar to the [[Hamilton-Jacobi equation]] that expresses the classical [[action functional]] $S$ and the [[canonical momentum]] \begin{displaymath} p \coloneqq \frac{\partial}{\partial x} S \end{displaymath} except that in addition to the ordinary [[potential energy]] $V$ there is an additional term \begin{displaymath} Q \coloneq \frac{\hbar^2}{2m} \frac{1}{\sqrt{\rho}}\frac{\partial^2}{\partial^2 x} \sqrt{\rho} \end{displaymath} which is unlike what may appar in an ordinary [[Hamilton-Jacobi equation]]. The perspective of Bohmian mechanics is to regard this as a correction of [[quantum physics]] to classical [[Hamilton-Jacobi theory]], it is then called the \emph{quantum potential}. Notice that unlike ordinary potentials, this ``quantum potential'' is a function of the density that is subject to the potential. (Notice that this works only away from the [[zero locus]] of $\rho$.) \item The second equation has the form of the [[continuity equation]] of the [[flow]] expressed by $\frac{1}{m}p$. \end{enumerate} (In the context of \emph{[[Bohmian mechanics]]} one regard this equivalent rewriting of the [[Schrödinger equation]] as providing a [[hidden variable theory]] formulation of [[quantum mechanics]].) \hypertarget{examples}{}\subsection*{{Examples}}\label{examples} \ldots{} \hypertarget{related_concepts}{}\subsection*{{Related concepts}}\label{related_concepts} \begin{itemize}% \item [[Tomonaga-Schwinger equation]] \item [[Schrödinger picture]] \item [[heat equation]] \item [[wave equation]], [[Klein-Gordon equation]] \item [[Dirac equation]] \end{itemize} \hypertarget{references}{}\subsection*{{References}}\label{references} Any introductory textbook about [[quantum mechanics]] will explain the Schr\"o{}dinger equation (from the viewpoint of physicists mostly). \begin{itemize}% \item Wikipedia: \href{http://en.wikipedia.org/wiki/Schr%C3%B6dinger_equation}{Schr\"o{}dinger equation} \end{itemize} [[!redirects Schrödinger's equation]] [[!redirects Schroedinger equation]] [[!redirects Schroedinger's equation]] \end{document}