\documentclass[12pt,titlepage]{article} \usepackage{amsmath} \usepackage{mathrsfs} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsthm} \usepackage{mathtools} \usepackage{graphicx} \usepackage{color} \usepackage{ucs} \usepackage[utf8x]{inputenc} \usepackage{xparse} \usepackage{hyperref} %----Macros---------- % % Unresolved issues: % % \righttoleftarrow % \lefttorightarrow % % \color{} with HTML colorspec % \bgcolor % \array with options (without options, it's equivalent to the matrix environment) % Of the standard HTML named colors, white, black, red, green, blue and yellow % are predefined in the color package. 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\newtheorem{prop}{Proposition} \newtheorem{cor}{Corollary} \newtheorem*{utheorem}{Theorem} \newtheorem*{ulemma}{Lemma} \newtheorem*{uprop}{Proposition} \newtheorem*{ucor}{Corollary} \theoremstyle{definition} \newtheorem{defn}{Definition} \newtheorem{example}{Example} \newtheorem*{udefn}{Definition} \newtheorem*{uexample}{Example} \theoremstyle{remark} \newtheorem{remark}{Remark} \newtheorem{note}{Note} \newtheorem*{uremark}{Remark} \newtheorem*{unote}{Note} %------------------------------------------------------------------- \begin{document} %------------------------------------------------------------------- \section*{thermodynamic limit} \hypertarget{context}{}\subsubsection*{{Context}}\label{context} \hypertarget{physics}{}\paragraph*{{Physics}}\label{physics} [[!include physicscontents]] \hypertarget{contents}{}\section*{{Contents}}\label{contents} \noindent\hyperlink{idea}{Idea}\dotfill \pageref*{idea} \linebreak \noindent\hyperlink{related_concepts}{Related concepts}\dotfill \pageref*{related_concepts} \linebreak \noindent\hyperlink{references}{References}\dotfill \pageref*{references} \linebreak \hypertarget{idea}{}\subsection*{{Idea}}\label{idea} In [[statistical physics]] the \emph{thermodynamic limit} denotes the limiting behaviour of a [[physical system]] that consists of many components ([[particles]]) as \begin{itemize}% \item the [[volume]] $V$ and the number $N$ of particles tends to [[infinity]]; \item the density ratio $\rho \coloneqq N/V$ approaches a constant value. \end{itemize} Many characteristic properties of macroscopic physical systems only appear in this limit, notably [[phase transitions]], [[universality classes]] and other [[critical phenomena]]. \hypertarget{related_concepts}{}\subsection*{{Related concepts}}\label{related_concepts} \begin{itemize}% \item [[universality class]] \item [[conformal bootstrap]] \item [[quantum lattice system]] \end{itemize} \hypertarget{references}{}\subsection*{{References}}\label{references} Reviews and introductions include \begin{itemize}% \item \emph{The theory of the thermodynamic limit} (\href{http://igitur-archive.library.uu.nl/dissertations/1957294/c8.pdf}{pdf}) \item Daniel F. Styer, \emph{What good is the thermodynamic limit?} American Journal of Physics -- January 2004 -- Volume 72, Issue 1, pp. 25 \textbf{Abstract} Statistical mechanics applies to large systems: technically, its results are exact only for infinitely large systems in ``the thermodynamic limit.'' The importance of this proviso is often minimized in undergraduate courses. This paper presents six paradoxes in statistical mechanics that can be resolved only by acknowledging the thermodynamic limit. For example, it demonstrates that the widely used microcanonical ``thin phase space limit'' must be taken after taking the thermodynamic limit. \item Ben Simons, \emph{Phase Transitions and Collective Phenomena} (\href{http://www.tcm.phy.cam.ac.uk/~bds10/phase.html}{web}) \item C. N. Yang and T. D. Lee , \emph{Statistical Theory of Equations of State and Phase Transitions. I. Theory of Condensation}, Phys. Rev. 87, 404--409 (1952) \end{itemize} [[!redirects thermodynamics limits]] [[!redirects phase transition]] [[!redirects phase transitions]] \end{document}