Hochschild-Kostant-Rosenberg I think. See also Hochschild cohomology.
http://mathoverflow.net/questions/35777/hochschild-and-cyclic-homology-of-smooth-varieties
http://ncatlab.org/nlab/show/Hochschild-Kostant-Rosenberg+theorem
Toen: Algebres simplicicales etc, file Toen web prepr rhamloop.pdf. Comparison between functions on derived loop spaces and de Rham theory. Take a smooth k-algebra, k aof char zero. Then (roughly) the de Rham algebra of A and the simplical algebra determine each other (functorial equivalence). Consequence: For a smooth k-scheme , the algebraic de Rham cohomology is identified with -equivariant functions on the derived loop space of . Conjecturally this should follow from a more general comparison between functions on the derived loop space and cyclic homology. Also functorial and multiplicative versions of HKR type thms on decompositions of Hochschild cohomology, for any separated k-scheme.
nLab page on HKR theorem