Introducing the idea that came to be known as Hawking radiation:
Stephen Hawking: Particle creation by black holes, Commun. Math. Phys. 43 (1975) 199–220 [doi:10.1007/BF02345020]
James B. Hartle, Stephen W. Hawking: Path-integral derivation of black-hole radiance, Phys. Rev. D 13 (1976) 2188 [doi:10.1103/PhysRevD.13.2188]
On the global structure of spacetime in the theory of gravity/general relativity (Penrose singularity theorem, …):
Stephen W. Hawking, George F. R. Ellis: The large scale structure of space-time, Cambridge Univ. Press (1973, 2010) [doi:10.1017/CBO9780511524646, Wikipedia entry]
Stephen Hawking, Roger Penrose, The Nature of Space and Time, Princeton University Press (1996) [ISBN 0-691-03791-4, arXiv:hep-th/9409195, Wikipedia entry]
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