Ab is the category of abelian groups. So, it has abelian groups as objects and group homomorphisms between these as morphisms.
can be made into a monoidal category in several ways, the most notable involving direct sum and tensor product of abelian groups. A monoid internal to is a ring, while a monoid in is just an abelian group (since is the coproduct in , so every object has a unique monoid structure with respect to it).
Categories enriched over are called pre-additive categories or sometimes just additive categories. If they satisfy an extra exactness condition they are called abelian categories.